reaction of 1, 1′, 2, 2′-tetrakis (phenylamino) ethane with glyoxal; synthesis of n2, n3, n7, n8, 1, 4, 5, 6, 9, 10 -decaphenyltetradecahydro - dipyrazino [2, 3-b: 2, 3-e] pyrazine-2, 3, 7, 8 -tetraamine and 5, 6 -bis (ethoxy) -n2, n3, 1, 4 -tetraphenylhexahydro -2, 3- pyrazinediamine
نویسندگان
چکیده
compound n2, n3, n7, n8, 1, 4, 5, 6, 9, 10-decaphenyltetradecahydrodipyrazino [2, 3-b: 2, 3-e] pyrazine-2, 3, 7, 8-tetraamine (4) was prepared by condensation of 1, 1′, 2, 2′-tetrakis (phenylamino) ethane (1d) and glyoxal in etoh or i-proh. also, reaction of 1d with glyoxal in equimolare in etoh resulted 5,6-bis (ethoxy)-n2, n3, 1, 4-tetraphenylhexahydro-2, 3-pyrazinediamine (5). the natures of products are sensitive to acidity, temperature and solvent. in acidic media, 4 and 5 are unstable and degraded to diimine 6.
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عنوان ژورنال:
iranian journal of chemistry and chemical engineering (ijcce)ناشر: iranian institute of research and development in chemical industries (irdci)-acecr
ISSN 1021-9986
دوره 24
شماره 2 2005
کلمات کلیدی
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